Postulates of Quantum Mechanics
Quantum mechanics is the description of the behavior of matter and light on an atomic scale. Between 1926 and 1927 Schrödinger, Heisenberg, Born, and Pauli developed a consistent description of the behavior of matter on a small scale. The following postulates summarize this description.
I. Wavefunction Postulates (Schrödinger)
- The dynamical state of a system of n particles is completely
defined by a wavefunction
Y(r1,r2
,...,rn;t)
= Y(r;t).
- The wavefunction evolves in time and space according to the
time dependent Schrödinger equation.
HY(r;t)
= i
dY(r;t)/dt
II. Operator Postulates (Born)
- The probability of finding a particle in the volume element
dV is given by the square of the wavefunction.
Y*(r;t) Y(r;t) dV
- For every observable property of the system, their corresponds
a linear Hermitian operator.
O
- The possible results of a single measurement of a physical observable
associated with an operator O is given by its eigen values.
on
O jn
= on jn
- The average value of a large number of observations of a given
state Y(r;t) is given by the
expectation value of the operator.
<O> = < Y(r;t)
|O| Y(r;t)>
III. Spin Postulates (Dirac and Pauli)
- Electrons posses an internal degree of freedom with properties
analogous to angular momentum whose z component assumes only two values
+
/2 or -
/2.
- Systems made up of many electrons are represented by a wavefunction
that is antisymmetric to the interchange of electron coordinates.
Y(r1,r2,
...,rn;t)
= -Y(r2,r1,
...,rn;t)