Postulates of Quantum Mechanics

Quantum mechanics is the description of the behavior of matter and light on an atomic scale. Between 1926 and 1927 Schrödinger, Heisenberg, Born, and Pauli developed a consistent description of the behavior of matter on a small scale. The following postulates summarize this description.

I. Wavefunction Postulates (Schrödinger)

  1. The dynamical state of a system of n particles is completely defined by a wavefunction
    Y(r1,r2 ,...,rn;t) = Y(r;t).

  2. The wavefunction evolves in time and space according to the time dependent Schrödinger equation.
    HY(r;t) = i dY(r;t)/dt

II. Operator Postulates (Born)

  1. The probability of finding a particle in the volume element dV is given by the square of the wavefunction.
    Y*(r;t) Y(r;t) dV

  2. For every observable property of the system, their corresponds a linear Hermitian operator.
    O

  3. The possible results of a single measurement of a physical observable associated with an operator O is given by its eigen values. on
    O jn = on jn

  4. The average value of a large number of observations of a given state Y(r;t) is given by the expectation value of the operator.
    <O> = < Y(r;t) |O| Y(r;t)>

III. Spin Postulates (Dirac and Pauli)

  1. Electrons posses an internal degree of freedom with properties analogous to angular momentum whose z component assumes only two values +/2 or -/2.

  2. Systems made up of many electrons are represented by a wavefunction that is antisymmetric to the interchange of electron coordinates.
    Y(r1,r2, ...,rn;t) = -Y(r2,r1, ...,rn;t)